作者
X Fontané, V Izquierdo-Roca, E Saucedo, S Schorr, VO Yukhymchuk, M Ya Valakh, A Pérez-Rodríguez, JR Morante
发表日期
2012/10/25
期刊
Journal of Alloys and Compounds
卷号
539
页码范围
190-194
出版商
Elsevier
简介
This work reports the analysis of the vibrational properties of stannite–kesterite Cu2(Fe,Zn)SnS4 compounds that has been performed by Raman scattering measurements. The detailed analysis of the experimental spectra has allowed determining the frequency and symmetry assignment of the main and weaker peaks from both stannite Cu2FeSnS4 (CFTS) and kesterite Cu2ZnSnS4 (CZTS) phases. The measurements performed in the kesterite CZTS samples have also revealed the presence of local inhomogeneities that are characterised by an additional peak in the spectra at about 331 cm−1. This peak has been related to the presence in these local regions of a high degree of disorder in the cation sublattice, in agreement with previous neutron diffraction analysis in similar samples. Finally, the spectra from the solid solution alloys show a one-mode behaviour of the main A/A1 peak with the chemical composition.
引用总数
201220132014201520162017201820192020202120222023202431735302323282917141696
学术搜索中的文章