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The Iberian Peninsula hosts the world-class Hg mining district of Almadén. Besides pre-Hercynian ore bodies, alpine-cycle Hg-bearing veins are also present in the eastern Iberian Ranges (Espadán deposits). We present both the first absolute ages (84±4 and 85±3 Ma) for a post-Hercynian Hg deposit in Spain, obtained from primary muscovites, and a complete compilation of published Mesozoic radiometric absolute ages of the Iberian Peninsula. We deduce that there are three main thermal episodes that affected the Iberian Peninsula, which have been revealed after the comparison among the magmatic, metamorphic and hydrothermal ages. Moreover, the Espadán hydrothermal system was active when both the Cretaceous alkalic magmatism took place in Southern Portugal and in the Pyrenees, and during the opening of the Bay of Biscay.