作者
Rahimeh Naviri Fallah, Saeid Azizian
发表日期
2012/1/1
期刊
Fuel processing technology
卷号
93
期号
1
页码范围
45-52
出版商
Elsevier
简介
The adsorption behavior of benzothiophene (BT), dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (DMDBT) from n-heptane was investigated onto activated carbon cloth (ACC) and its modified forms at 30°C in batch condition. ACC was modified by HNO3, (NH4)2S2O8, H2SO4, HCl and NaOH at ambient temperature. The adsorbents were characterized using nitrogen adsorption/desorption. It was found that the adsorbents are mainly microporous but differ in their surface chemistry, which is related to the effect of oxidizing agent. The adsorption process was studied from both equilibrium and kinetics point of view. The equilibrium experimental data were fitted to the Langmuir, Freundlich and Langmuir–Freundlich by non-linear method. Among the tested adsorbents, the modified ACC with HNO3 (ACC-HNO3) had the highest capacity for adsorption of DBT. Kinetic characterization of the adsorption …
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