作者
Miriam Elser, Ru-Jin Huang, Robert Wolf, Jay G Slowik, Qiyuan Wang, Francesco Canonaco, Guohui Li, Carlo Bozzetti, Kaspar R Daellenbach, Yu Huang, Renjian Zhang, Zhengqiang Li, Junji Cao, Urs Baltensperger, Imad El-Haddad, André SH Prévôt
发表日期
2016/3/11
期刊
Atmospheric Chemistry and Physics
卷号
16
期号
5
页码范围
3207-3225
出版商
Copernicus Publications
简介
During winter 2013–2014 aerosol mass spectrometer (AMS) measurements were conducted for the first time with a novel PM (particulate matter with aerodynamic diameter  2.5 µm) lens in two major cities of China: Xi'an and Beijing. We denote the periods with visibility below 2 km as extreme haze and refer to the rest as reference periods. During the measurements in Xi'an an extreme haze covered the city for about a week and the total non-refractory (NR)-PM mass fraction reached peak concentrations of over 1000 µg m. During the measurements in Beijing two extreme haze events occurred, but the temporal extent and the total concentrations reached during these events were lower than in Xi'an. Average PM concentrations of 537  146 and 243  47 µg m (including NR species and equivalent black carbon, eBC) were recorded during the extreme haze events in Xi'an and Beijing, respectively. During the reference periods the measured average concentrations were 140  99 µg m in Xi'an and 75  61 µg m in Beijing. The relative composition of the NR-PM evolved substantially during the extreme haze periods, with increased contributions of the inorganic components (mostly sulfate and nitrate). Our results suggest that the high relative humidity present during the extreme haze events had a strong effect on the increase of sulfate mass (via aqueous phase oxidation of sulfur dioxide). Another relevant characteristic of the extreme haze is the size of the measured particles. During the extreme haze events, the AMS showed much larger particles, with a volume weighted mode at about 800 to 1000 nm, in contrast to about 400 nm during reference periods. These large …
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