作者
Tianyi Qin, Yingying Huang, Kangning Zhu, Jiahao Wang, Chengjun Pan, Bin Liu, Lei Wang
发表日期
2019/10/17
期刊
Analytica Chimica Acta
卷号
1076
页码范围
125-130
出版商
Elsevier
简介
Developing fluorescent sensors with ability of monitoring gaseous nerve agents in a sensitive and selective manner is of great importance due to the extreme toxicity and volatility of organophosphorus nerve agents. Herein we reported a novel oxime-modified flavonoid sensor and carefully investigated its sensing behavior towards nerve agent simulants, diethylchlorophosphate (DCP). In the presence of DCP, a remarkable fluorescence enhancement accompanied with emission color change could be observed by naked eyes in solution. The response time was less than 90 s and LOD value was calculated as 0.78 μmol/L in solution. The sensing mechanism could be ascribed to the specific reaction between halophosphate and hydroxyl group of oxime. Furthermore, sensor strips have been successfully constructed by using PEG as matrix with a simple preparation process, and also achieved the sensitive and …
引用总数
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