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Atmospheric brown carbon (BrC) is an important contributor to the radiative forcing of climate by organic aerosols. Because of the molecular diversity of BrC compounds and their dynamic transformations, it is challenging to predictively understand BrC optical properties. OH radical and O₃ reactions, together with photolysis, lead to diminished light absorption and lower warming effects of biomass burning BrC. The effects of night-time aging on the optical properties of BrC aerosols are less known. To address this knowledge gap, night-time NO₃ radical chemistry with tar aerosols from wood pyrolysis was investigated in a flow reactor. This study shows that the optical properties of BrC change because of transformations driven by reactions with the NO₃ radical that form new absorbing species and lead to significant absorption enhancement over the ultraviolet–visible (UV-vis) range. The overnight aging increases the …