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The atomic structure of liquid-quenched amorphous Al₉₀Fe_xCe_10−x (x = 5, 7) was studied by diffraction method using X-rays from a synchrotron source. The diffraction data were Fourier-transformed to obtain the atomic pair-density function, and were compared with those obtained by the pulsed neutron scattering to determine the AlFe and AlCe coordination and the extent of compositional short range ordering. The accuracy of the pair-density function, limited by both statistical and systematic errors, is discussed. It was found that both Fe and Ce atoms show strong compositional short range ordering, amounting to 70–80% of the maximum ordering possible. While Ce atoms form a dilute dense random packing substructure, the substructure of Fe atoms and the surrounding Al was found to be substantially different from the random packing.