作者
Jared N King, Vanessa J Lee, Susanna Ahola, Ville‐Veikko Telkki, Tyler Meldrum
发表日期
2016/4/11
期刊
Angewandte Chemie International Edition
卷号
55
期号
16
页码范围
5040-5043
简介
Laplace NMR (LNMR) consists of relaxation and diffusion measurements providing detailed information about molecular motion and interaction. Here we demonstrate that ultrafast single‐ and multidimensional LNMR experiments, based on spatial encoding, are viable with low‐field, single‐sided magnets with an inhomogeneous magnetic field. This approach shortens the experiment time by one to two orders of magnitude relative to traditional experiments, and increases the sensitivity per unit time by a factor of three. The reduction of time required to collect multidimensional data opens significant prospects for mobile chemical analysis using NMR. Particularly tantalizing is future use of hyperpolarization to increase sensitivity by orders of magnitude, allowed by single‐scan approach.
引用总数
201620172018201920202021202220232024169338681
学术搜索中的文章
JN King, VJ Lee, S Ahola, VV Telkki, T Meldrum - Angewandte Chemie International Edition, 2016