作者
Xuejin Yang, Laura M Murphy, Farihah M Haque, Scott M Grayson, Andrew J Boydston
发表日期
2021
期刊
Polymer Chemistry
卷号
12
期号
19
页码范围
2860-2867
出版商
Royal Society of Chemistry
简介
We have achieved breakthroughs for the efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP). Molecular weight control from 1 to 16 kDa can be targeted in a straightforward manner. Assisted by this method, the Tg–Mn dependence of linear pDCPD is investigated and reported for the first time.
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X Yang, LM Murphy, FM Haque, SM Grayson… - Polymer Chemistry, 2021