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Cobalt sulfide precipitates, key phases in the natural biogeochemistry of cobalt and in relevant remediation and resource recovery processes, are poorly defined under low-temperature aqueous conditions. Here, we systematically studied Co (Fe) sulfides precipitated and aged in environmentally relevant solutions, defined by different combinations of pH, initial cobalt to iron ratios ([Co]_aq/[Fe]_aq), with/without S⁰, and the presence/absence of sulfate-reducing bacteria. The initial abiogenic precipitates were composed exclusively of amorphous Co sulfide nanoparticles (CoS·xH₂O) that were stable in anoxic solution for 2 months, with estimated log K* values 1–5 orders of magnitude higher than that previously reported for Co sulfides. The addition of S⁰, in combination with acidic pH and elevated temperature (60 °C), resulted in recrystallization of the amorphous precipitates into nanocrystalline jaipurite (hexagonal …