作者
Anjaiah Sheelam, Dalton L Glasco, Jeffrey G Bell
发表日期
2023/4/1
期刊
Chemical Engineering Journal
卷号
461
页码范围
141900
出版商
Elsevier
简介
Despite the high safety and low-cost of aqueous zinc-bromide batteries (AZBBs), their widespread application in portable and stationary energy storage systems is hindered by deleterious zinc-dendrite growth and cross-diffusion of tribromide (Br3) ions. Here, we, for the first time demonstrate the effect of Lorentz force using internal magnets to retain the reversible capacity for mitigated cross-diffusion of Br3, dendrite-free zinc deposition, enhanced cycle life, improved voltage efficiency and energy efficiency of AZBBs via magnetohydrodynamics. Of the magnetic field strengths investigated (0 – 70 ± 1 mT), cells incorporating 50 ± 1 mT achieved a high energy efficiency of 88.8 % (coulombic efficiency of 99.3 %) with a small decay of 7.6 % after 550 cycles. Interestingly, batteries with internal magnets resist self-discharge and exhibit an improved rate-capability (up to 3C rate) compared to batteries without magnets …
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