作者
Top Archie Dela Pena, Jafar I Khan, Neha Chaturvedi, Ruijie Ma, Zengshan Xing, Julien Gorenflot, Anirudh Sharma, Fai Lun Ng, Derya Baran, He Yan, Frédéric Laquai, Kam Sing Wong
发表日期
2021/9/3
期刊
ACS Energy Letters
卷号
6
期号
10
页码范围
3408-3416
出版商
American Chemical Society
简介
Energy losses significantly reduce the open-circuit voltage among current state-of-the-art organic solar cells (OSCs), which limits the further enhancement of their power conversion efficiencies (PCEs). In this study, the bulk heterojunction blends of PM6 donor and halogenated nonfullerene acceptors (NFAs) display a trade-off between radiative energy losses, i.e., charge transfer state (CTS) radiative energy loss (ΔErad) and the loss associated with CTS formation from acceptor singlet excitons (ΔECTEL). Similarly, a trade-off between ΔErad and the nonradiative energy loss (ΔEnr) is found, reflecting a competition in radiative and nonradiative charge recombination pathways. Further, the energy levels of relaxed CTS (ECTEL) are shown to exhibit dependence on morphologically induced energetic traps, suggesting that it should not be associated merely to blend constituents. Interestingly, these correlations extend …
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