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This work reports the synthesis of high temperature proton conductors based on zirconium phosphate and imidazolium-based ionic liquids. This material is evaluated for high temperature proton exchange membrane fuel cells applications operating at 200 °C. The characterization results show high proton conductivity, enhanced water uptake properties, changes in structure, and exfoliation in zirconium phosphates crystal layers upon the introduction of the ionic liquid. The proton conductivity results demonstrate that there is an optimum amount of ionic liquid that can be introduced into zirconium phosphates to enhance its conductivity beyond which, the conductivity starts to decrease. At the optimum conditions, the addition of ionic liquids enhances the proton conductivity of the zirconium phosphates material by orders of magnitude. The results show a high proton conductivity the order of 10⁻² S cm⁻¹ at room …