作者
Arturo Carranza, María G Pérez-García, Kunlin Song, George M Jeha, Zhenyu Diao, Rongying Jin, Nina Bogdanchikova, Armando F Soltero, Mauricio Terrones, Qinglin Wu, John A Pojman, Josué D Mota-Morales
发表日期
2016/11/16
期刊
ACS Applied Materials & Interfaces
卷号
8
期号
45
页码范围
31295-31303
出版商
American Chemical Society
简介
We report an alternative green strategy based on deep-eutectic solvents (DES) to deliver multiwalled carbon nanotubes (MWCNTs) for a bottom-up approach that allows for the selective interfacial functionalization of nonaqueous poly(high internal phase emulsions), poly(HIPEs). The formation and polymerization of methacrylic and styrenic HIPEs were possible through stabilization with nitrogen doped carbon nanotube (CNX) and surfactant mixtures using a urea-choline chloride DES as a delivering phase. Subtle changes in CNX concentration (less than 0.2 wt % to the internal phase) produced important changes in the macroporous monolith functionalization, which in turn led to increased monolith hydrophobicity and pore openness. These materials displayed great oleophilicity with water contact angles as high as 140° making them apt for biodiesel, diesel, and gasoline fuel sorption applications. Overall, styrene …
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