作者
Tomoyuki Kamata, Michinori Sumimoto, Shunsuke Shiba, Ryoji Kurita, Osamu Niwa, Dai Kato
发表日期
2019
期刊
Nanoscale
卷号
11
期号
18
页码范围
8845-8854
出版商
Royal Society of Chemistry
简介
The musty odor compound geosmin was electrochemically detected by using Pt nanoparticle (PtNP)-embedded nanocarbon (Pt–C) films formed with unbalanced magnetron (UBM) co-sputtering. The sputtered Pt components formed NPs (typically 1.53–4.75 nm in diameter) spontaneously in the carbon films, owing to the poor intermiscibility of Pt with carbon. The surface concentrations of PtNPs embedded in the nanocarbon film were widely controllable (Pt = 4.8–35.9 at%) by regulating the target powers of the Pt and carbon individually. The obtained film had a flat surface (Ra = 0.17–0.18 nm) despite the fact the PtNPs were partially exposed at the surface. Compared with a Pt film electrode, some Pt–C films exhibited higher electrode activity against geosmin although the surface Pt concentrations of these Pt–C films were much lower than that of the Pt film electrode, thanks to the wider potential window and lower …
引用总数
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