作者
Niranjana Jaya Prakash, Dhivya Shanmugarajan, Xungai Wang, Balasubramanian Kandasubramanian
发表日期
2022/12/1
期刊
Sustainable Chemistry and Pharmacy
卷号
30
页码范围
100902
出版商
Elsevier
简介
The dielectric properties of silk coupled with the selective heating nature of microwaves have been employed in this work for the extirpation of gummy sericin layer from the surface of silk fibroin (S.F.). We studied the physicomechanical properties of intermittent microwave degummed silk fibers (MWS) systematically in comparison with the traditional sodium carbonate method. The experimental results validated the effective removal of sericin layer, with a degumming ratio of 25.5% on microwave irradiation, accounting to the breakage of disulfide bonds, on explosion of hot spots generated by the entrapped water molecules. The segmental motion and conformational reorientation of polymeric chains on administering microwaves, further improved the crystallinity of material, causing augmentation in Young's modulus and ultimate tensile strength of degummed silk by 115.4% and 268.8%, respectively, in comparison …
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