作者
Fernando J Beltran, Francisco J Rivas, Lidia A Fernandez, Pedro M Álvarez, Ramón Montero-de-Espinosa
发表日期
2002/12/11
期刊
Industrial & engineering chemistry research
卷号
41
期号
25
页码范围
6510-6517
出版商
American Chemical Society
简介
The ozonation kinetics of oxalic acid in water in the presence of an activated carbon has been investigated at acid pH. The presence of the activated carbon significantly enhances the degradation rate of oxalic acid if compared to single ozonation and single adsorption. According to total organic carbon measurements, nearly complete mineralization of oxalic acid can be achieved depending on the experimental conditions. The presence of tert-butyl alcohol, which scarcely adsorbs on the carbon surface at the conditions investigated, led to a significant reduction of the oxalic acid removal rate. Consequently, experimental results suggest that the reaction proceeds in the water phase between oxalic acid and oxidant species, likely hydroxyl radicals, coming from the ozone decomposition on the carbon surface. The proposed mechanism yielded a first-order kinetics with respect to ozone, close to the 0.8 order …
引用总数
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FJ Beltrán, FJ Rivas, LA Fernández, PM Álvarez… - Industrial & engineering chemistry research, 2002