作者
Hannes Hempel, Tom J Savenjie, Martin Stolterfoht, Jens Neu, Michele Failla, Vaisakh C Paingad, Petr Kužel, Edwin J Heilweil, Jacob A Spies, Markus Schleuning, Jiashang Zhao, Dennis Friedrich, Klaus Schwarzburg, Laurens DA Siebbeles, Patrick Dörflinger, Vladimir Dyakonov, Ryuzi Katoh, Min Ji Hong, John G Labram, Maurizio Monti, Edward Butler‐Caddle, James Lloyd‐Hughes, Mohammad M Taheri, Jason B Baxter, Timothy J Magnanelli, Simon Luo, Joseph M Cardon, Shane Ardo, Thomas Unold
发表日期
2022/4
期刊
Advanced Energy Materials
卷号
12
期号
13
页码范围
2102776
简介
Mobilities and lifetimes of photogenerated charge carriers are core properties of photovoltaic materials and can both be characterized by contactless terahertz or microwave measurements. Here, the expertise from fifteen laboratories is combined to quantitatively model the current‐voltage characteristics of a solar cell from such measurements. To this end, the impact of measurement conditions, alternate interpretations, and experimental inter‐laboratory variations are discussed using a (Cs,FA,MA)Pb(I,Br)3 halide perovskite thin‐film as a case study. At 1 sun equivalent excitation, neither transport nor recombination is significantly affected by exciton formation or trapping. Terahertz, microwave, and photoluminescence transients for the neat material yield consistent effective lifetimes implying a resistance‐free JV‐curve with a potential power conversion efficiency of 24.6 %. For grainsizes above ≈20 nm, intra‐grain …
引用总数
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