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Among the potential fates of indoor air pollutants are a variety of physical and chemical interactions with indoor surfaces. In deterministic mathematical models of indoor air quality, these interactions are usually represented as a first-order loss process, with the loss rate coefficient given as the product of the surface-to-volume ratio of the room times a deposition velocity. In this paper, the validity of this representation of surface-loss mechanisms is critically evaluated. From a theoretical perspective, the idea of a deposition velocity is consistent with the following representation of an indoor air environment. Pollutants are well-mixed throughout a core region which is separated from room surfaces by boundary layers. Pollutants migrate through the boundary layers by a combination of diffusion (random motion resulting from collisions with surrounding gas molecules), advection (transport by net motion of the fluid), and, in some cases, other transport mechanisms. The rate of pollutant loss to a surface is governed by a combination of the rate of transport through the boundary layer and the rate of reaction at the surface. The deposition velocity expresses the pollutant flux density (mass or moles deposited per area per time) to the surface divided by the pollutant concentration in the core region. This concept has substantial value to the extent that the flux density is proportional to core concentration. Empirically, the problem of human exposure to ozone in commercial buildings has been successfully modeled by using the deposition velocity to parameterize ozone removal onto indoor surfaces. The concept has also been applied in investigations of the indoor …