查看文章

A dissipative particle dynamics (DPD) simulation is performed to study the properties of water/benzene/caprolactam (W/B/CPL) system in the absence or presence of different non-ionic surfactants. The interaction parameters involved in the constructed coarse-grained model are determined by combining two solubility-parameter models and all-atom molecular dynamics. By using the DPD method, we first show that the interfacial tensions in the W/B/CPL system can be quantitatively predicted and compared with available experimental and other theoretical data. Secondly, by calculating the density profile of CPL and the efficiency of the surfactant at various conditions, we demonstrate that (i) unlike Traube׳s rule, the efficiency of the surfactant does not always improve with an increase in its hydrophobic tail length, and due to the accumulation of CPL at the interface, this tail length effect becomes nearly negligible when …