作者
Ali Coskun, M Deniz Yilmaz, Engin U Akkaya
发表日期
2007/2/15
期刊
Organic Letters
卷号
9
期号
4
页码范围
607-609
出版商
American Chemical Society
简介
Aryl-substituted boratriazaindacenes (Aza-Bodipy's) are a new class of dyes with long wavelength absorption and emissions. We now report the first application of these dyes in metal ion sensing. 2-Pyridyl substituents at positions 1 and 7 create a well-defined pocket for metal ion binding. The chemosensor described here is selective for Hg(II) ions, and both absorption and emission spectra display large changes that would allow ratiometric sensing.
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