作者
Xiaowen Feng, Corine Mathonière, Ie-Rang Jeon, Mathieu Rouzières, Andrew Ozarowski, Michael L Aubrey, Miguel I Gonzalez, Rodolphe Clérac, Jeffrey R Long
发表日期
2013/10/23
期刊
Journal of the American Chemical Society
卷号
135
期号
42
页码范围
15880-15884
出版商
American Chemical Society
简介
Molecules exhibiting bistability have been proposed as elementary binary units (bits) for information storage, potentially enabling fast and efficient computing. In particular, transition metal complexes can display magnetic bistability via either spin-crossover or single-molecule magnet behavior. We now show that the octahedral iron(II) complexes in the molecular salt [Fe(1-propyltetrazole)6](BF4)2, when placed in its high-symmetry form, can combine both types of behavior. Light irradiation under an applied magnetic field enables fully reversible switching between an S = 0 state and an S = 2 state with either up (MS = +2) or down (MS = −2) polarities. The resulting tristability suggests the possibility of using molecules for ternary information storage in direct analogy to current binary systems that employ magnetic switching and the magneto-optical Kerr effect as write and read mechanisms.
引用总数
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学术搜索中的文章
X Feng, C Mathonière, IR Jeon, M Rouzières… - Journal of the American Chemical Society, 2013