查看文章

A new metal–organic framework, Fe-BTTri (Fe₃[(Fe₄Cl)₃(BTTri)₈]₂·18CH₃OH, H₃BTTri =1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene)), is found to be highly selective in the adsorption of CO over a variety of other gas molecules, making it extremely effective, for example, in the removal of trace CO from mixtures with H₂, N₂, and CH₄. This framework not only displays significant CO adsorption capacity at very low pressures (1.45 mmol/g at just 100 μbar), but, importantly, also exhibits readily reversible CO binding. Fe-BTTri utilizes a unique spin state change mechanism to bind CO in which the coordinatively unsaturated, high-spin Fe^II centers of the framework convert to octahedral, low-spin Fe^II centers upon CO coordination. Desorption of CO converts the Fe^II sites back to a high-spin ground state, enabling the facile regeneration and recyclability of the material. This spin state change is supported by characterization via …