作者
Jing Sun, David Alam, Rahman Daiyan, Hassan Masood, Tianqi Zhang, Renwu Zhou, Patrick J Cullen, Emma C Lovell, Ali Rouhollah Jalili, Rose Amal
发表日期
2021
期刊
Energy & Environmental Science
卷号
14
期号
2
页码范围
865-872
出版商
Royal Society of Chemistry
简介
From nurturing living organisms to feeding billions of people, the transformation of atmospheric nitrogen to ammonia (NH3) is essential to sustain life on earth. In nature, bacteria and plants can produce ammonia from air and water at ambient conditions via nitrogen fixation processes. To follow this feat, we couple plasma-driven nitrogen oxides intermediary (NOx) generation and their electrocatalytic reduction to pave the way for scalable green ammonia at ambient conditions. We developed a non-thermal plasma bubble column reactor that brings together dual reactor configuration with multiple discharge schemes and bubble dynamic control to generate NOx intermediaries at low specific energy consumption of 3.8 kW h mol−1. The NOx intermediaries were converted to ammonia at a rate of 23.2 mg h−1 (42.1 nmol cm−2 s−1), using a scalable electrolyzer operating at a low cell voltage of 1.4 V, current densities of …
引用总数
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