作者
Tadanori Koga, N Jiang, P Gin, MK Endoh, S Narayanan, LB Lurio, SK Sinha
发表日期
2011/11/21
期刊
Physical review letters
卷号
107
期号
22
页码范围
225901
出版商
American Physical Society
简介
We report the origin of the effect of nanoscale confinement on the local viscosity of entangled polystyrene (PS) films at temperatures far above the glass transition temperature. By using marker x-ray photon correlation spectroscopy with gold nanoparticles embedded in the PS films prepared on solid substrates, we have determined the local viscosity as a function of the distance from the polymer-substrate interface. The results show the impact of a very thin adsorbed layer (∼ 7 nm in thickness) even without specific interactions of the polymer with the substrate, overcoming the effect of a surface mobile layer at the air-polymer interface and thereby resulting in a significant increase in the local viscosity as approaching the substrate interface.
引用总数
201220132014201520162017201820192020202120222023202410131217132728152110141111
学术搜索中的文章