作者
Matej Kanduč, Ali Naji, Jan Forsman, Rudolf Podgornik
发表日期
2010/3/23
期刊
The Journal of chemical physics
卷号
132
期号
12
页码范围
124701
出版商
AIP Publishing
简介
We reformulate the theory of strong electrostatic coupling in order to describe an asymmetric electrolyte solution of monovalent salt ions and polyvalent counterions using field-theoretical techniques and Monte Carlo simulations. The theory is based on an asymmetric treatment of the different components of the electrolyte solution. The weak coupling Debye–Hückel approach is used in order to describe the monovalent salt ions while a strong coupling approach is used to tackle the polyvalent counterions. This combined weak-strong coupling approach effectively leads to dressed interactions between polyvalent counterions and thus directly affects the correlation attraction mediated by polyvalent counterions between like-charged objects. The general theory is specifically applied to a system composed of two uniformly charged plane-parallel surfaces in the presence of salt and polyvalent counterions. In the strong …
引用总数
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学术搜索中的文章
M Kanduč, A Naji, J Forsman, R Podgornik - The Journal of chemical physics, 2010