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Flexible electromagnetic interference (EMI) shielding materials with excellent thermal conductivities and Joule heating performances are of urgent demand in the communication industry, artificial intelligence, and wearable electronics. In this work, highly conductive silver nanowires (AgNWs) were prepared using the polyol method. Cellulose sheets were then prepared by dissolving natural cotton in a green and efficient NaOH/urea aqueous solution. Finally, multifunctional flexible EMI shielding AgNWs/cellulose films were fabricated based on vacuum-assisted filtration and hot-pressing. AgNWs are evenly embedded in the inner cellulose matrix and overlap with each other to form a 3D network. AgNWs/cellulose films, with a thickness of 44.5 μm, obtain the superior EMI shielding effectiveness of 101 dB, which is the highest value ever reported for shielding materials with the same thickness. In addition, AgNWs …