作者
SH Baek, Marshall Luban, A Lascialfari, E Micotti, Y Furukawa, Ferdinando Borsa, Joris van Slageren, Andrea Cornia
发表日期
2004/10/1
期刊
Physical Review B—Condensed Matter and Materials Physics
卷号
70
期号
13
页码范围
134434
出版商
American Physical Society
简介
We present new and refined data for the magnetic field and temperature dependence of the proton spin-lattice relaxation rate in antiferromagnetic molecular rings as well as a new explicit scaling formula that accurately reproduces our data. The key ingredients of our formulation are (1) a reduced relaxation rate, , given by , where is the differential susceptibility, is a fitting constant, and is the proton Larmor frequency, and (2) a temperature-dependent correlation frequency which at low is given by , that we identify as a lifetime broadening of the energy levels of the exchange-coupled paramagnetic spins due to spin-acoustic phonon coupling. The main consequences are (1) has a local maximum for fixed and variable that is proportional to ; the maximum occurs at the temperature for which ; (2) for low …
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SH Baek, M Luban, A Lascialfari, E Micotti, Y Furukawa… - Physical Review B—Condensed Matter and Materials …, 2004