作者
Ensan Waatriah ES Shahrin, Nur Alimatul Hakimah Narudin, Nurulizzatul Ningsheh M Shahri, Muhammad Nur, Jun-Wei Lim, Muhammad Roil Bilad, Abdul Hanif Mahadi, Jonathan Hobley, Anwar Usman
发表日期
2023/3/1
期刊
Emerging Contaminants
卷号
9
期号
1
页码范围
100199
出版商
Elsevier
简介
Adsorptive removal and dynamic interaction of three different pharmaceutical pollutants, namely rifampicin (RIF), streptomycin (STM), and ibuprofen (IBU) onto chitosan were systematically investigated using a batch adsorption technique at different processing parameters. In this study, chitosan was derived from mud-crab shells, as an innovative way to use the waste from marine foods as adsorbents. The kinetics, intraparticle diffusion, mechanism, and thermodynamics of the adsorption were systematically evaluated and analyzed using kinetic models, Boyd mass transfer and Weber–Morris intraparticle diffusion models, Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin isotherm models, and the Gibbs equation. The adsorption isotherm of the larger molecules, RIF and STM, could be explained by the Langmuir isotherm model, in contrast, that of IBU, which is a much smaller molecule, followed the …
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