作者
Paul JM Smeets, Kang Rae Cho, Nico AJM Sommerdijk, James J De Yoreo
发表日期
2017/10
期刊
Advanced Functional Materials
卷号
27
期号
40
页码范围
1701658
简介
Growth by oriented assembly of nanoparticles is a widely reported phenomenon for many crystal systems. While often deduced through morphological analyses, direct evidence for this assembly behavior is limited and, in the calcium carbonate (CaCO3) system, has recently been disputed. However, in the absence of a particle‐based pathway, the mechanism responsible for the creation of the striking morphologies that appear to consist of subparticles is unclear. Therefore, in situ atomic force microscopy is used to investigate the growth of calcite crystals in solutions containing a polymer additive known for its ability to generate crystal morphologies associated with mesocrystal formation. It is shown that classical growth processes that begin with impurity pinning of atomic steps, leading to stabilization of new step directions, creation of pseudo‐facets, and extreme surface roughening, can produce a microscale …
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