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Potassium plays an important role in the metabolism of plants, growth, development and yields. Worldwide, KCl is commonly used as source of K fertilizer in agricultural crops. The present experiment was taken up to assess the response of various sources of K on physiological attributes, yield and quality parameters of sugarcane. Treatments were no K application, potassium ammonium sulphate (H₄KNO₄S-9:0:30:20, NPKS ratio), slow release K fertilizer (0:0:45:0), sulphate of potash/potassium sulphate (K₂SO₄-0:0:50:17.5), muriate of potash (KCl-0:0:50:0) and muriate of potash (KCl) + elemental S @ 40 kg ha⁻¹. Application of K₂SO₄ recorded 15.8% improvement in tiller population (during peak tillering stage) and 22.2% improvement in dry matter accumulation (at the harvest stage) over the KCl. About 12.33–24.16% increments in crop growth rate and the highest net photosynthetic rate (19.91 µmol m …