作者
SK Nechaev, AN Semenov, MK Koleva
发表日期
1987/1/1
期刊
Physica A: Statistical Mechanics and its Applications
卷号
140
期号
3
页码范围
506-520
出版商
North-Holland
简介
On the basis of the model “polymer chain in an array of obstacles” the influence of the topology effects on the dynamics of concentrated polymer systems is investigated theoretically. The 1/z-expansion (where z is the coordinational number of the lattice of obstacles) is proposed for this problem. By means of this expansion the diffusion coefficient of a linear unclosed polymer chain is calculated. The equilibrium properties of linear closed chain (i.e. ring) unentangled with either of the edges of the lattice are investigated in detail. In particular, it is shown that the diffusion coefficient D of the center of mass of closed chain consisting of N links is proportional to N−5/2.
引用总数
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SK Nechaev, AN Semenov, MK Koleva - Physica A: Statistical Mechanics and its Applications, 1987