作者
Guangmin Zhou, Da-Wei Wang, Feng Li, Lili Zhang, Na Li, Zhong-Shuai Wu, Lei Wen, Gao Qing Lu, Hui-Ming Cheng
发表日期
2010/9/28
期刊
Chemistry of materials
卷号
22
期号
18
页码范围
5306-5313
出版商
American Chemical Society
简介
A well-organized flexible interleaved composite of graphene nanosheets (GNSs) decorated with Fe3O4 particles was synthesized through in situ reduction of iron hydroxide between GNSs. The GNS/Fe3O4 composite shows a reversible specific capacity approaching 1026 mA h g−1 after 30 cycles at 35 mA g−1 and 580 mAh g−1 after 100 cycles at 700 mA g−1as well as improved cyclic stability and excellent rate capability. The multifunctional features of the GNS/Fe3O4 composite are considered as follows: (i) GNSs play a “flexible confinement” function to enwrap Fe3O4 particles, which can compensate for the volume change of Fe3O4 and prevent the detachment and agglomeration of pulverized Fe3O4, thus extending the cycling life of the electrode; (ii) GNSs provide a large contact surface for individual dispersion of well-adhered Fe3O4 particles and act as an excellent conductive agent to provide a highway for …
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