作者
Jorge Kurchan, Giorgio Parisi, Pierfrancesco Urbani, Francesco Zamponi
发表日期
2013/10/24
期刊
The Journal of Physical Chemistry B
卷号
117
期号
42
页码范围
12979-12994
出版商
American Chemical Society
简介
We consider the theory of the glass phase and jamming of hard spheres in the large space dimension limit. Building upon the exact expression for the free-energy functional obtained previously, we find that the random first order transition (RFOT) scenario is realized here with two thermodynamic transitions: the usual Kauzmann point associated with entropy crisis and a further transition at higher pressures in which a glassy structure of microstates is developed within each amorphous state. This kind of glass–glass transition into a phase dominating the higher densities was described years ago by Elisabeth Gardner, and may well be a generic feature of RFOT. Microstates that are small excitations of an amorphous matrixseparated by low entropic or energetic barriersthus emerge naturally, and modify the high pressure (or low temperature) limit of the thermodynamic functions.
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