作者
Giancarlo Ruocco, Francesco Sciortino, F Zamponi, Cristiano De Michele, Tullio Scopigno
发表日期
2004/6/8
期刊
The Journal of chemical physics
卷号
120
期号
22
页码范围
10666-10680
出版商
American Institute of Physics
简介
The concept of fragility provides a possibility to rank different supercooled liquids on the basis of the temperature dependence of dynamic and/or thermodynamic quantities. We recall here the definitions of kinetic and thermodynamic fragility proposed in the last years and discuss their interrelations. At the same time we analyze some recently introduced models for the statistical properties of the potential energy landscape. Building on the Adam–Gibbs relation, which connects structural relaxation times to configurational entropy, we analyze the relation between statistical properties of the landscape and fragility. We call attention to the fact that the knowledge of number, energy depth, and shape of the basins of the potential energy landscape may not be sufficient for predicting fragility. Finally, we discuss two different possibilities for generating strong behavior.
引用总数
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G Ruocco, F Sciortino, F Zamponi, C De Michele… - The Journal of chemical physics, 2004