作者
JD Eick, RJ Good, AW Neumann
发表日期
1975/11/1
期刊
Journal of Colloid and Interface Science
卷号
53
期号
2
页码范围
235-248
出版商
Academic Press
简介
The thermodynamics of an idealized rough surface is treated, using the geometry of a vertical plate partially immersed in a liquid. Gravity is included explicitly in the theory. The results of this treatment are more general than those of previous studies and are more easily extended to other surface topographies. Some novel results are found, such as a delineation of the conditions under which a macroscopic contact angle of 180° will result from geometric properties of the solid surface. On rough surfaces consisting of material for which, if smooth, the equilibrium contact angle would be different from 90°, the slopes of the asperities will be a very important factor in determining the effective equilibrium contact angles.
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JD Eick, RJ Good, AW Neumann - Journal of Colloid and Interface Science, 1975