作者
Joseph P Patterson, Ana M Sanchez, Nikos Petzetakis, Thomas P Smart, Thomas H Epps III, Ian Portman, Neil R Wilson, Rachel K O'Reilly
发表日期
2012
期刊
Soft Matter
卷号
8
期号
12
页码范围
3322-3328
出版商
Royal Society of Chemistry
简介
Block copolymers are well-known to self-assemble into a range of 3-dimensional morphologies. However, due to their nanoscale dimensions, resolving their exact structure can be a challenge. Transmission electron microscopy (TEM) is a powerful technique for achieving this, but for polymeric assemblies chemical fixing/staining techniques are usually required to increase image contrast and protect specimens from electron beam damage. Graphene oxide (GO) is a robust, water-dispersable, and nearly electron transparent membrane: an ideal support for TEM. We show that when using GO supports no stains are required to acquire high contrast TEM images and that the specimens remain stable under the electron beam for long periods, allowing sample analysis by a range of electron microscopy techniques. GO supports are also used for further characterization of assemblies by atomic force microscopy. The …
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