A Highly Reactive Mononuclear Non-Heme Manganese (IV)–Oxo Complex That Can Activate the Strong C–H Bonds of Alkanes X Wu, MS Seo, KM Davis, YM Lee, J Chen, KB Cho, YN Pushkar, W Nam Journal of the American Chemical Society 133 (50), 20088-20091, 2011 | 227 | 2011 |
To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes KB Cho, H Hirao, S Shaik, W Nam Chemical Society Reviews 45 (5), 1197-1210, 2016 | 204 | 2016 |
A mononuclear nonheme iron (IV)-oxo complex which is more reactive than cytochrome P450 model compound I MS Seo, NH Kim, KB Cho, JE So, SK Park, M Clémancey, ... Chemical Science 2 (6), 1039-1045, 2011 | 201 | 2011 |
A Mononuclear Non-Heme Manganese (IV)–Oxo Complex Binding Redox-Inactive Metal Ions J Chen, YM Lee, KM Davis, X Wu, MS Seo, KB Cho, H Yoon, YJ Park, ... Journal of the American Chemical Society 135 (17), 6388-6391, 2013 | 193 | 2013 |
Synthesis and reactivity of a mononuclear non-haem cobalt (IV)-oxo complex B Wang, YM Lee, WY Tcho, S Tussupbayev, ST Kim, Y Kim, MS Seo, ... Nature communications 8 (1), 14839, 2017 | 162 | 2017 |
Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme FeIVO Complexes KB Cho, X Wu, YM Lee, YH Kwon, S Shaik, W Nam Journal of the American Chemical Society 134 (50), 20222-20225, 2012 | 151 | 2012 |
Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron (III)–peroxo complexes S Bang, YM Lee, S Hong, KB Cho, Y Nishida, MS Seo, R Sarangi, ... Nature chemistry 6 (10), 934-940, 2014 | 148 | 2014 |
Enhanced Electron-Transfer Reactivity of Nonheme Manganese (IV)–Oxo Complexes by Binding Scandium Ions H Yoon, YM Lee, X Wu, KB Cho, R Sarangi, W Nam, S Fukuzumi Journal of the American Chemical Society 135 (24), 9186-9194, 2013 | 140 | 2013 |
A Manganese (V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion S Hong, YM Lee, M Sankaralingam, AK Vardhaman, YJ Park, KB Cho, ... Journal of the American Chemical Society 138 (27), 8523-8532, 2016 | 127 | 2016 |
Ligand Topology Effect on the Reactivity of a Mononuclear Nonheme Iron (IV)-Oxo Complex in Oxygenation Reactions S Hong, YM Lee, KB Cho, K Sundaravel, J Cho, MJ Kim, W Shin, W Nam Journal of the American Chemical Society 133 (31), 11876-11879, 2011 | 104 | 2011 |
Water as an Oxygen Source: Synthesis, Characterization, and Reactivity Studies of a Mononuclear Nonheme Manganese (IV) Oxo Complex SC Sawant, X Wu, J Cho, KB Cho, SH Kim, MS Seo, YM Lee, M Kubo, ... Angewandte Chemie International Edition 49 (44), 8190-8194, 2010 | 104 | 2010 |
Interplay of experiment and theory in elucidating mechanisms of oxidation reactions by a nonheme RuIVO complex SN Dhuri, KB Cho, YM Lee, SY Shin, JH Kim, D Mandal, S Shaik, W Nam Journal of the American Chemical Society 137 (26), 8623-8632, 2015 | 92 | 2015 |
Theoretical Investigations into C–H Bond Activation Reaction by Nonheme MnIVO Complexes: Multistate Reactivity with No Oxygen Rebound KB Cho, S Shaik, W Nam The Journal of Physical Chemistry Letters 3 (19), 2851-2856, 2012 | 86 | 2012 |
External Electric Field Can Control the Catalytic Cycle of Cytochrome P450cam: A QM/MM Study W Lai, H Chen, KB Cho, S Shaik The Journal of Physical Chemistry Letters 1 (14), 2082-2087, 2010 | 85 | 2010 |
Mechanistic insight into the hydroxylation of alkanes by a nonheme iron (v)–oxo complex E Kwon, KB Cho, S Hong, W Nam Chemical Communications 50 (42), 5572-5575, 2014 | 75 | 2014 |
Determination of Spin Inversion Probability, H-Tunneling Correction, and Regioselectivity in the Two-State Reactivity of Nonheme Iron (IV)-Oxo Complexes YH Kwon, BK Mai, YM Lee, SN Dhuri, D Mandal, KB Cho, Y Kim, S Shaik, ... The Journal of Physical Chemistry Letters 6 (8), 1472-1476, 2015 | 74 | 2015 |
Dioxygen Activation by a Non-Heme Iron (II) Complex: Theoretical Study toward Understanding Ferric–Superoxo Complexes H Chen, KB Cho, W Lai, W Nam, S Shaik Journal of Chemical Theory and Computation 8 (3), 915-926, 2012 | 73 | 2012 |
A Mononuclear Non-Heme High-Spin Iron (III)–Hydroperoxo Complex as an Active Oxidant in Sulfoxidation Reactions YM Kim, KB Cho, J Cho, B Wang, C Li, S Shaik, W Nam Journal of the American Chemical Society 135 (24), 8838-8841, 2013 | 72 | 2013 |
Oxidation of Tertiary Amines by Cytochrome P450—Kinetic Isotope Effect as a Spin‐State Reactivity Probe C Li, W Wu, KB Cho, S Shaik Chemistry-A European Journal 15 (34), 8492-8503, 2009 | 72 | 2009 |
Mechanistic dichotomies in redox reactions of mononuclear metal–oxygen intermediates S Fukuzumi, KB Cho, YM Lee, S Hong, W Nam Chemical Society Reviews 49 (24), 8988-9027, 2020 | 68 | 2020 |