Enantioselective synthesis of trisubstituted allenyl–B (pin) compounds by phosphine–Cu-catalyzed 1, 3-enyne hydroboration. insights regarding stereochemical integrity of Cu … Y Huang, J Del Pozo, S Torker, AH Hoveyda Journal of the American Chemical Society 140 (7), 2643-2655, 2018 | 153 | 2018 |
Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre J Lee, S Radomkit, S Torker, J Del Pozo, AH Hoveyda Nature chemistry 10 (1), 99-108, 2018 | 112 | 2018 |
Catalytic enantioselective boryl and silyl substitution with trifluoromethyl alkenes: scope, utility, and mechanistic nuances of Cu–F β-elimination PHS Paioti, J Del Pozo, MS Mikus, J Lee, MJ Koh, F Romiti, S Torker, ... Journal of the American Chemical Society 141 (50), 19917-19934, 2019 | 102 | 2019 |
Delayed catalyst function enables direct enantioselective conversion of nitriles to NH2-amines S Zhang, J del Pozo, F Romiti, Y Mu, S Torker, AH Hoveyda Science 364 (6435), 4551, 2019 | 87 | 2019 |
Different strategies for designing dual-catalytic enantioselective processes: from fully cooperative to non-cooperative systems F Romiti, J Del Pozo, PHS Paioti, SA Gonsales, X Li, FWW Hartrampf, ... Journal of the American Chemical Society 141 (45), 17952-17961, 2019 | 84 | 2019 |
Stille coupling involving bulky groups feasible with gold cocatalyst. J delPozo, D Carrasco, MH Pérez‐Temprano, M García‐Melchor, ... Angewandte Chemie 125 (8), 2013 | 70 | 2013 |
Racemic Vinylallenes in Catalytic Enantioselective Multicomponent Processes. Rapid Generation of Complexity through 1, 6‐Conjugate Additions AH Hoveyda, Y Huang, S Torker, X Li, J del Pozo Angewandte Chemie International Edition, 2019 | 54* | 2019 |
The Negishi catalysis: full study of the complications in the transmetalation step and consequences for the coupling products J del Pozo, G Salas, R Álvarez, JA Casares, P Espinet Organometallics 35 (20), 3604-3611, 2016 | 48 | 2016 |
Ru-Based Catechothiolate Complexes Bearing an Unsaturated NHC Ligand: Effective Cross-Metathesis Catalysts for Synthesis of (Z)-α,β-Unsaturated Esters … Z Liu, C Xu, J Del Pozo, S Torker, AH Hoveyda Journal of the American Chemical Society 141 (17), 7137-7146, 2019 | 47 | 2019 |
Promoting difficult carbon–carbon couplings: which ligand does best? E Gioria, J Del Pozo, JM Martínez‐Ilarduya, P Espinet Angewandte Chemie 128 (42), 13470-13474, 2016 | 45 | 2016 |
Speciation of ZnMe2, ZnMeCl, and ZnCl2 in Tetrahydrofuran (THF), and Its Influence on Mechanism Calculations of Catalytic Processes J Del Pozo, M Pérez-Iglesias, R Álvarez, A Lledós, JA Casares, P Espinet ACS Catalysis 7 (5), 3575-3583, 2017 | 32 | 2017 |
The decisive role of ligand metathesis in Au/Pd bimetallic catalysis JA Casares, P Espinet Chemical Communications 49 (65), 7246-7248, 2013 | 31 | 2013 |
Copper–Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis Y Sun, Y Zhou, Y Shi, J Del Pozo, S Torker, AH Hoveyda Journal of the American Chemical Society 141 (30), 12087-12099, 2019 | 30 | 2019 |
Streamlined catalytic enantioselective synthesis of α-substituted β, γ-unsaturated ketones and either of the corresponding tertiary homoallylic alcohol diastereomers J Pozo, S Zhang, F Romiti, S Xu, RP Conger, AH Hoveyda Journal of the American Chemical Society 142 (42), 18200-18212, 2020 | 29 | 2020 |
Organometallic Nucleophiles and Pd: What Makes ZnMe2 Different? Is Au Like Zn? J delPozo, E Gioria, JA Casares, R Álvarez, P Espinet Organometallics 34 (13), 3120-3128, 2015 | 28 | 2015 |
Diastereo-and enantioselective synthesis of compounds with a trifluoromethyl-and fluoro-substituted carbon centre S Xu, J Del Pozo, F Romiti, Y Fu, BK Mai, RJ Morrison, KA Lee, S Hu, ... Nature chemistry 14 (12), 1459-1469, 2022 | 19 | 2022 |
Olefin Insertion Versus Cross-Coupling in trans-[Pd(Ar)X(AsPh3)2] Complexes (X = I, F, CF3) Treated with a Phosphine-EWOlefin Ligand to Induce Ar–X Coupling J del Pozo, E Gioria, P Espinet Organometallics 36 (15), 2884-2890, 2017 | 10 | 2017 |
In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient J delPozo, JA Casares, P Espinet Chemistry–A European Journal 22 (12), 4274-4284, 2016 | 10 | 2016 |
Understanding the Use of Phosphine-(EWO) Ligands in Negishi Cross-Coupling: Experimental and Density Functional Theory Mechanistic Study E Gioria, J del Pozo, A Lledós, P Espinet Organometallics 40 (14), 2272-2282, 2021 | 9 | 2021 |
Click processes orthogonal to CuAAC and SuFEx forge selectively modifiable fluorescent linkers PHS Paioti, KE Lounsbury, F Romiti, M Formica, V Bauer, C Zandonella, ... Nature Chemistry 16 (3), 426-436, 2024 | 7 | 2024 |