Palladium‐Catalyzed Direct Alkynylation of N‐Vinylacetamides YH Xu, QC Zhang, T He, FF Meng, TP Loh Advanced Synthesis & Catalysis 356 (7), 1539-1543, 2014 | 67 | 2014 |
Synthesis of multi-substituted pyrroles using enamides and alkynes catalyzed by Pd (OAc) 2 with molecular oxygen as an oxidant YH Xu, T He, QC Zhang, TP Loh Chemical Communications 50 (21), 2784-2786, 2014 | 62 | 2014 |
Silylium‐Ion‐Promoted (5+ 1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration T He, G Wang, V Bonetti, HFT Klare, M Oestreich Angewandte Chemie 132 (29), 12284-12289, 2020 | 29 | 2020 |
B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes PW Long, T He, M Oestreich Organic Letters 22 (18), 7383-7386, 2020 | 27 | 2020 |
Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis T He, HFT Klare, M Oestreich Journal of the American Chemical Society 144 (11), 4734-4738, 2022 | 24 | 2022 |
Enantioselective Construction of Si‐Stereogenic Center via Rhodium‐Catalyzed Intermolecular Hydrosilylation of Alkene T He, LC Liu, WP Ma, B Li, QW Zhang, W He Chemistry–A European Journal 26 (71), 17011-17015, 2020 | 23 | 2020 |
Silylium-ion regeneration by protodesilylation enables Friedel–Crafts alkylation with less isomerization and no defunctionalization T He, HFT Klare, M Oestreich ACS Catalysis 11 (19), 12186-12193, 2021 | 20 | 2021 |
Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and … T He, G Wang, PW Long, S Kemper, E Irran, HFT Klare, M Oestreich Chemical Science 12 (2), 569-575, 2021 | 19 | 2021 |
Rhodium‐Catalyzed Intermolecular trans‐Disilylation of Alkynones with Unactivated Disilanes T He, LC Liu, L Guo, B Li, QW Zhang, W He Angewandte Chemie 130 (34), 11034-11038, 2018 | 19 | 2018 |
Copper‐Catalyzed Trifunctionalization of Alkynes: Rapid Formation of Oxindoles Bearing Geminal Diboronates T He, B Li, LC Liu, J Wang, WP Ma, GY Li, QW Zhang, W He Chemistry–A European Journal 25 (4), 966-970, 2019 | 17 | 2019 |
Intermolecular Carbosilylation of α‐Olefins with C(sp3)−C(sp) Bond Formation Involving Silylium‐Ion Regeneration T He, ZW Qu, HFT Klare, S Grimme, M Oestreich Angewandte Chemie International Edition 61 (24), e202203347, 2022 | 15 | 2022 |
Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol T He, HFT Klare, M Oestreich Journal of the American Chemical Society 145 (6), 3795-3801, 2023 | 14 | 2023 |
Arenium-ion-catalysed halodealkylation of fully alkylated silanes T He, HFT Klare, M Oestreich Nature 623 (7987), 538-543, 2023 | 13 | 2023 |
Rhodium‐Catalyzed Intermolecular Silylation of Csp−H by Silacyclobutanes T He, B Li, L Liu, W Ma, W He Chemistry–A European Journal 27 (18), 5648-5652, 2021 | 13 | 2021 |
Skeletal Rearrangements Involving Cyclopropyl-and Alkene-Stabilized Silylium Ions PW Long, T He, HFT Klare, M Oestreich Synlett 35 (09), 941-951, 2024 | 1 | 2024 |
Intermolekulare Carbosilylierung von α‐Olefinen mit C (sp3)− C (sp)‐Bindungsknüpfung unter Neubildung von Silyliumionen T He, ZW Qu, HFT Klare, S Grimme, M Oestreich Angewandte Chemie 134 (24), e202203347, 2022 | 1 | 2022 |
Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes T Randt, T He, HFT Klare, M Oestreich Synthesis 56 (19), 3054-3062, 2024 | | 2024 |
B (C₆F₅) ₃-Catalyzed Hydrosilylation of Vinylcyclopropanes PW Long, T He, M Oestreich | | 2020 |
Palladium-catalyzed direct alkynylation of N-vinylacetamides TP Loh, YH Xu, QC Zhang, T He, FF Meng | | 2014 |
1. General experimental details YH Xu, T He, QC Zhanga, TP Loh | | |