Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp3)–C … AQ Cusumano, BM Stoltz, WA Goddard III Journal of the American Chemical Society 142 (32), 13917-13933, 2020 | 44 | 2020 |
Multireference description of nickel–aryl homolytic bond dissociation processes in photoredox catalysis DA Cagan, GD Stroscio, AQ Cusumano, RG Hadt The Journal of Physical Chemistry A 124 (48), 9915-9922, 2020 | 33 | 2020 |
Ir-catalyzed asymmetric allylic alkylation of dialkyl malonates enabling the construction of enantioenriched all-carbon quaternary centers FA Moghadam, EF Hicks, ZP Sercel, AQ Cusumano, MD Bartberger, ... Journal of the American Chemical Society 144 (18), 7983-7987, 2022 | 24 | 2022 |
3-Hydroxy-1, 5-dihydro-2H-pyrrol-2-ones as novel antibacterial scaffolds against methicillin-resistant Staphylococcus aureus AQ Cusumano, JG Pierce Bioorganic & medicinal chemistry letters 28 (16), 2732-2735, 2018 | 20 | 2018 |
Direct access to highly functionalized heterocycles through the condensation of cyclic imines and α-oxoesters AQ Cusumano, MW Boudreau, JG Pierce The Journal of organic chemistry 82 (24), 13714-13721, 2017 | 18 | 2017 |
Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids TJ Fulton, AQ Cusumano, EJ Alexy, YE Du, H Zhang, KN Houk, BM Stoltz Journal of the American Chemical Society 142 (52), 21938-21947, 2020 | 17 | 2020 |
The transition metal catalyzed [π2s+ π2s+ σ2s+ σ2s] pericyclic reaction: Woodward–Hoffmann rules, aromaticity, and electron flow AQ Cusumano, WA Goddard III, BM Stoltz Journal of the American Chemical Society 142 (45), 19033-19039, 2020 | 16 | 2020 |
Probing trends in enantioinduction via substrate design: Palladium-catalyzed decarboxylative allylic alkylation of α-enaminones DC Duquette, AQ Cusumano, L Lefoulon, JT Moore, BM Stoltz Organic letters 22 (13), 4966-4969, 2020 | 11 | 2020 |
Identifying the Imperative Role of Metal–Olefin Interactions in Catalytic C–O Reductive Elimination from Nickel (II) TD Lohrey, AQ Cusumano, WA Goddard III, BM Stoltz ACS catalysis 11 (16), 10208-10222, 2021 | 6 | 2021 |
Enantioselective 1, 3-Dipolar Cycloadditions of α-Methylene Lactams to Construct Spirocycles Y Nishiura, KJ Gonzalez, AQ Cusumano, BM Stoltz Organic Letters 25 (35), 6469-6473, 2023 | 5 | 2023 |
Mechanism of Ni-Catalyzed Photochemical Halogen Atom-Mediated C(sp3)–H Arylation AQ Cusumano, BC Chaffin, AG Doyle Journal of the American Chemical Society, 2024 | 4 | 2024 |
Divergent Catalysis: Catalytic Asymmetric [4+ 2] Cycloaddition of Palladium Enolates KN Flesch, AQ Cusumano, PJ Chen, CS Strong, SR Sardini, YE Du, ... Journal of the American Chemical Society 145 (20), 11301-11310, 2023 | 4 | 2023 |
Investigations of an unexpected [2+ 2] photocycloaddition in the synthesis of (−)-scabrolide A from quantum mechanics calculations T Zhang, AQ Cusumano, NJ Hafeman, SA Loskot, CE Reimann, SC Virgil, ... The Journal of Organic Chemistry 87 (21), 14115-14124, 2022 | 4 | 2022 |
Synthetic strategy toward ineleganolide: A cautionary tale AQ Cusumano, KN Houk, BM Stoltz Tetrahedron 93, 132289, 2021 | 3 | 2021 |
Origins of Enhanced Enantioselectivity in the Pd-Catalyzed Decarboxylative Allylic Alkylation of N-Benzoyl Lactams AQ Cusumano, T Zhang, WA Goddard III, BM Stoltz Catalysts 13 (9), 1258, 2023 | 2 | 2023 |
Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α, β-Unsaturated Lactams: Enantioselective Construction of All-Carbon Quaternary Stereocenters in … T Zhang, Y Nishiura, AQ Cusumano, BM Stoltz Organic Letters 25 (35), 6479-6484, 2023 | 2 | 2023 |
Molecular Dynamics Investigations of Dienolate [4+ 2] Reactions PJ Chen, AQ Cusumano, KN Flesch, CS Strong, WA Goddard III, ... Journal of the American Chemical Society 146 (18), 12758-12765, 2024 | | 2024 |
Asymmetric Pericyclic Transformations from Reactive Palladium Intermediates AQ Cusumano California Institute of Technology, 2024 | | 2024 |