| High-precision simultaneous determination of multiple small kinetic isotope effects at natural abundance DA Singleton, AA Thomas Journal of the American Chemical Society 117 (36), 9357-9358, 1995 | 471 | 1995 |
| A case study of the mechanism of alcohol-mediated Morita Baylis–Hillman reactions. The importance of experimental observations RE Plata, DA Singleton Journal of the American Chemical Society 137 (11), 3811-3826, 2015 | 462 | 2015 |
| Experimental and theoretical kinetic isotope effects for asymmetric dihydroxylation. Evidence supporting a rate-limiting “(3+ 2)” cycloaddition AJ DelMonte, J Haller, KN Houk, KB Sharpless, DA Singleton, T Strassner, ... Journal of the American Chemical Society 119 (41), 9907-9908, 1997 | 349 | 1997 |
| Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism DA Singleton, C Hang, MJ Szymanski, MP Meyer, AG Leach, KT Kuwata, ... Journal of the American Chemical Society 125 (5), 1319-1328, 2003 | 328 | 2003 |
| Synchronous or asynchronous? An “experimental” transition state from a direct comparison of experimental and theoretical kinetic isotope effects for a Diels− Alder reaction BR Beno, KN Houk, DA Singleton Journal of the American Chemical Society 118 (41), 9984-9985, 1996 | 220 | 1996 |
| Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene BR Ussing, C Hang, DA Singleton Journal of the American Chemical Society 128 (23), 7594-7607, 2006 | 214 | 2006 |
| Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations DT Nowlan, TM Gregg, HML Davies, DA Singleton Journal of the American Chemical Society 125 (51), 15902-15911, 2003 | 199 | 2003 |
| Outer-sphere direction in iridium C–H borylation PC Roosen, VA Kallepalli, B Chattopadhyay, DA Singleton, ... Journal of the American Chemical Society 134 (28), 11350-11353, 2012 | 195 | 2012 |
| Experimental geometry of the epoxidation transition state DA Singleton, SR Merrigan, J Liu, KN Houk Journal of the American Chemical Society 119 (14), 3385-3386, 1997 | 193 | 1997 |
| Phenomenon of optical self-purification of chiral non-racemic compounds VA Soloshonok, H Ueki, M Yasumoto, S Mekala, JS Hirschi, DA Singleton Journal of the American Chemical Society 129 (40), 12112-12113, 2007 | 191 | 2007 |
| Dynamics and the failure of transition state theory in alkene hydroboration Y Oyola, DA Singleton Journal of the American Chemical Society 131 (9), 3130-3131, 2009 | 180 | 2009 |
| Reinvestigation of the isotope effects for the Claisen and aromatic Claisen rearrangements: The nature of the Claisen transition states MP Meyer, AJ DelMonte, DA Singleton Journal of the American Chemical Society 121 (47), 10865-10874, 1999 | 173 | 1999 |
| Ir-catalyzed ortho-borylation of phenols directed by substrate–ligand electrostatic interactions: a combined experimental/in silico strategy for optimizing weak interactions B Chattopadhyay, JE Dannatt, IL Andujar-De Sanctis, KA Gore, ... Journal of the American Chemical Society 139 (23), 7864-7871, 2017 | 160 | 2017 |
| Control elements in dynamically determined selectivity on a bifurcating surface JB Thomas, JR Waas, M Harmata, DA Singleton Journal of the American Chemical Society 130 (44), 14544-14555, 2008 | 160 | 2008 |
| Distinction between aminium cation radical and protic acid catalyzed Diels-Alder reactions PG Gassman, DA Singleton Journal of the American Chemical Society 106 (25), 7993-7994, 1984 | 157 | 1984 |
| “Concerted” Transition State, Stepwise Mechanism. Dynamics Effects in C2-C6 Enyne Allene Cyclizations T Bekele, CF Christian, MA Lipton, DA Singleton Journal of the American Chemical Society 127 (25), 9216-9223, 2005 | 143 | 2005 |
| A few molecules can control the enantiomeric outcome. Evidence supporting absolute asymmetric synthesis using the Soai asymmetric autocatalysis DA Singleton, LK Vo Organic Letters 5 (23), 4337-4339, 2003 | 143 | 2003 |
| 13C Kinetic Isotope Effects for the Addition of Lithium Dibutylcuprate to Cyclohexenone. Reductive Elimination Is Rate-Determining DE Frantz, DA Singleton, JP Snyder Journal of the American Chemical Society 119 (14), 3383-3384, 1997 | 141 | 1997 |
| Dynamically complex [6+ 4] and [4+ 2] cycloadditions in the biosynthesis of spinosyn A A Patel, Z Chen, Z Yang, O Gutiérrez, H Liu, KN Houk, DA Singleton Journal of the American Chemical Society 138 (11), 3631-3634, 2016 | 138 | 2016 |
| Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents BA Vanchura, SM Preshlock, PC Roosen, VA Kallepalli, RJ Staples, ... Chemical communications 46 (41), 7724-7726, 2010 | 132 | 2010 |
Doug E. FrantzMax and Minnie Tomerlin Voelcker Distinguished Professor of Chemistry, UTSA在 utsa.edu 的电子邮件经过验证
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