Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst AA Toutov, WB Liu, KN Betz, A Fedorov, BM Stoltz, RH Grubbs Nature 518 (7537), 80-84, 2015 | 399 | 2015 |
Alkali Metal-Hydroxide-Catalyzed C(sp)–H Bond silylation AA Toutov, KN Betz, DP Schuman, WB Liu, A Fedorov, BM Stoltz, ... Journal of the American Chemical Society 139 (4), 1668-1674, 2017 | 98 | 2017 |
Sodium hydroxide catalyzed dehydrocoupling of alcohols with hydrosilanes AA Toutov, KN Betz, MC Haibach, AM Romine, RH Grubbs Organic letters 18 (22), 5776-5779, 2016 | 80 | 2016 |
A potassium tert-butoxide and hydrosilane system for ultra-deep desulfurization of fuels AA Toutov, M Salata, A Fedorov, YF Yang, Y Liang, R Cariou, KN Betz, ... Nature Energy 2 (3), 1-7, 2017 | 72 | 2017 |
Catalytic C–H bond silylation of aromatic heterocycles AA Toutov, WB Liu, KN Betz, BM Stoltz, RH Grubbs Nature protocols 10 (12), 1897-1903, 2015 | 51 | 2015 |
Intermolecular sp3-C–H Amination for the Synthesis of Saturated Azacycles KN Betz, ND Chiappini, J Du Bois Organic letters 22 (5), 1687-1691, 2019 | 32 | 2019 |
Transition-metal-free silylation of aromatic compounds RH Grubbs, A Fedorov, A Toutov, K Betz US Patent 9,000,167, 2015 | 21 | 2015 |
Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates T Godou, C Chauvier, P Thuéry, T Cantat Synlett 28 (18), 2473-2477, 2017 | 16 | 2017 |
Silylation of aromatic heterocycles by disilanes using potassium alkoxide catalysts A Toutov, W Liu, BM Stoltz, RH Grubbs, K Betz, DP Schuman US Patent 9,556,080, 2017 | 16 | 2017 |
Silylation of aromatic heterocycles by earth abundant transition-metal-free catalysts A Toutov, K Betz, A Fedorov, BM Stoltz, W Liu, RH Grubbs US Patent 9,809,607, 2017 | 14 | 2017 |
Pincer Ruthenium Catalyzed Intramolecular Silylation of C (sp2)–H Bonds H Fang, Q He, G Liu, Z Huang Synlett 28 (18), 2468-2472, 2017 | 11 | 2017 |
Laser power-meter comparison at far-infrared wavelengths and terahertz frequencies J Lehman, M Dowell, NB Popovic, K Betz, E Grossman Metrologia 49 (4), 583, 2012 | 9 | 2012 |
Metal-Free Ammonium Iodide Catalyzed Oxidative Dehydrocoupling of Silanes with Alcohols Y Yuan, PS Kumar, S Guo Synlett 28 (13), 1620-1623, 2017 | 7 | 2017 |
Silylation of aromatic heterocycles by disilanes using potassium alkoxide catalysts A Toutov, W Liu, BM Stoltz, RH Grubbs, K Betz, DP Schuman US Patent 9,764,995, 2017 | 6 | 2017 |
Hydroxide-catalyzed formation of silicon-oxygen bonds by dehydrogenative coupling of hydrosilanes and alcohols A Toutov, K Betz, AM Romine, RH Grubbs US Patent 10,259,831, 2019 | 5 | 2019 |
Patent Appl XB Liu, RH Grubbs, BM Stoltz, K Betz, DP Schuman WO/2016/100606, 2016. Google Scholar There is no corresponding record for …, 2006 | 4 | 2006 |
Preparation of silylamines by the dehydrogeative coupling of N—H and Si—H bonds A Toutov, K Betz, A Fedorov, BM Stoltz, W Liu, RH Grubbs US Patent 10,125,153, 2018 | 3 | 2018 |
Base-catalyzed silylation of terminal alkyne C—H bonds A Toutov, K Betz, BM Stoltz, W Liu, RH Grubbs US Patent 9,556,206, 2017 | 3 | 2017 |
Preparation of aromatic-substituted silylamines by the dehydrogenative coupling of aromatic-substituted amine N—H and Si—H bonds AA Toutov, KN Betz, AM Romine, RH Grubbs US Patent 10,781,221, 2020 | 2 | 2020 |
Silylations of aromatic substrates with base-activated organosilanes RH Grubbs, A Fedorov, A Toutov, KN Betz US Patent 11,230,520, 2022 | 1 | 2022 |