A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem: Regioselective Catalytic Direct Arylation of Pyridine N-Oxides LC Campeau, S Rousseaux, K Fagnou Journal of the American Chemical Society 127 (51), 18020-18021, 2005 | 632 | 2005 |
Palladium (0)-catalyzed arylative dearomatization of phenols S Rousseaux, J García-Fortanet, MA Del Aguila Sanchez, SL Buchwald Journal of the American Chemical Society 133 (24), 9282-9285, 2011 | 321 | 2011 |
Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides S Rousseaux, SI Gorelsky, BKW Chung, K Fagnou Journal of the American Chemical Society 132 (31), 10692-10705, 2010 | 283 | 2010 |
Intramolecular palladium-catalyzed alkane C− H arylation from aryl chlorides S Rousseaux, M Davi, J Sofack-Kreutzer, C Pierre, CE Kefalidis, E Clot, ... Journal of the American Chemical Society 132 (31), 10706-10716, 2010 | 238 | 2010 |
Selective carbon–carbon bond cleavage of cyclopropanols TR McDonald, LR Mills, MS West, SAL Rousseaux Chemical Reviews 121 (1), 3-79, 2020 | 188 | 2020 |
Self-assembly of Russian doll concentric porphyrin nanorings SAL Rousseaux, JQ Gong, R Haver, B Odell, TDW Claridge, LM Herz, ... Journal of the American Chemical Society 137 (39), 12713-12718, 2015 | 116 | 2015 |
Caterpillar track complexes in template‐directed synthesis and correlated molecular motion S Liu, DV Kondratuk, SAL Rousseaux, G Gil‐Ramírez, MC O'Sullivan, ... Angewandte Chemie International Edition 54 (18), 5355-5359, 2015 | 113 | 2015 |
Palladium (0)-catalyzed cyclopropane C–H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives S Rousseaux, B Liégault, K Fagnou Chemical Science 3 (1), 244-248, 2012 | 112 | 2012 |
Decarboxylative ketone aldol reactions: Development and mechanistic evaluation under metal-free conditions N Blaquiere, DG Shore, S Rousseaux, K Fagnou The Journal of Organic Chemistry 74 (16), 6190-6198, 2009 | 95 | 2009 |
Ni-catalyzed reductive cyanation of aryl halides and phenol derivatives via transnitrilation LR Mills, JM Graham, P Patel, SAL Rousseaux Journal of the American Chemical Society 141 (49), 19257-19262, 2019 | 88 | 2019 |
Modern developments in the chemistry of homoenolates LR Mills, SAL Rousseaux European Journal of Organic Chemistry 2019 (1), 8-26, 2019 | 72 | 2019 |
Ni-catalyzed β-alkylation of cyclopropanol-derived homoenolates LR Mills, C Zhou, E Fung, SAL Rousseaux Organic letters 21 (21), 8805-8809, 2019 | 64 | 2019 |
Electrophilic zinc homoenolates: synthesis of cyclopropylamines from cyclopropanols and amines LR Mills, LM Barrera Arbelaez, SAL Rousseaux Journal of the American Chemical Society 139 (33), 11357-11360, 2017 | 61 | 2017 |
Metal-Free Synthesis of Unsymmetrical Ureas and Carbamates from CO2 and Amines via Isocyanate Intermediates Y Ren, SAL Rousseaux The Journal of Organic Chemistry 83 (2), 913-920, 2018 | 58 | 2018 |
CACHE (Critical Assessment of Computational Hit-finding Experiments): A public–private partnership benchmarking initiative to enable the development of computational methods … S Ackloo, R Al-Awar, RE Amaro, CH Arrowsmith, H Azevedo, RA Batey, ... Nature Reviews Chemistry 6 (4), 287-295, 2022 | 50 | 2022 |
The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp3)–O Arylation LR Mills, JJ Monteith, G dos Passos Gomes, A Aspuru-Guzik, ... Journal of the American Chemical Society 142 (30), 13246-13254, 2020 | 43 | 2020 |
Design of an electron-withdrawing benzonitrile ligand for Ni-catalyzed cross-coupling involving tertiary nucleophiles R Mills, R Edjoc, S Rousseaux Journal of the American Chemical Society 143 (27), 10422-10428, 2021 | 37 | 2021 |
Nickel-catalyzed cyanation of benzylic and allylic pivalate esters NWM Michel, ADM Jeanneret, H Kim, SAL Rousseaux The Journal of Organic Chemistry 83 (19), 11860-11872, 2018 | 32 | 2018 |
Chiral aryl–copper (III) electrophiles: new opportunities in catalytic enantioselective arylations and domino processes S Rousseaux, E Vrancken, JM Campagne Angew Chem Int Ed 51, 10934-10935, 2012 | 32 | 2012 |
Kinetic Resolution of Quaternary and Tertiary β‐Hydroxy Esters DJ Schipper, S Rousseaux, K Fagnou Angewandte Chemie International Edition 48 (44), 8343-8347, 2009 | 30 | 2009 |