Acid-base equilibrium constants for 2, 4-dinitrophenol and some aliphatic amines in non-aqueous solvents

RG Pearson, DC Vogelsong - Journal of the American Chemical …, 1958 - ACS Publications
… ammonia,7 but not for the alkyl amines, the missing data being the … equilibrium constants
for several amines in some non-aqueous solvents using 2,4-dinitrophenol as the reference acid

Comparison of Basicity of Aliphatic Amines in Different Solvents

C Li, TD Stewart - Journal of the American Chemical Society, 1937 - ACS Publications
acid by the solvent rather than a spontaneous dissociation followed by solvation. Table II gives
the equilibrium constant, … the ratio of the basic dissociation constant of diethylamine to that …

On the modelling of multicomponent acid extraction with long‐chain aliphatic amines

S Stenström, S Wingefors - The Canadian Journal of Chemical …, 1988 - Wiley Online Library
… The activity of sulphuric acid based on the stoichiometric activity coefficient is … Wilson
calculated equilibrium constants for the extraction of sulphuric acid with TOA dissolved in benzene …

Thermodynamics of ionization and solution of aliphatic amines in water

FM Jones, EM Arnett - Progress in Physical Organic Chemistry, 1974 - Wiley Online Library
… for the best-studied aliphatic amines in water. Although we shall make a few introductory
comments on the base strengths of the aliphatic amines in water and nonaqueous solvents, we …

Kinetics of the formation of imines from isobutyraldehyde and primary aliphatic amines with polar substituents

J Hine, FA Via - Journal of the American Chemical Society, 1972 - ACS Publications
Equilibrium constants for the formation of carbinolamine plus imine based on total aldehyde
… used (the solid circles in Figure 2) shows that equilibrium constants for addition of amines to …

Specific effects of dimethyl sulfoxide on the relative basicities of aliphatic amines

A Reyes, RM Scott - The Journal of Physical Chemistry, 1980 - ACS Publications
… The base strength of amines in solventsystems containing dimethyl sulfoxide (Me2SO) is
studied. Equilibrium constants for the Bronsted acid-base reaction of various amines with p-…

The mechanism of hydrolysis of Schiff bases derived from aliphatic amines

EH Cordes, WP Jencks - Journal of the American Chemical …, 1963 - ACS Publications
… Both the rate and equilibrium constants for the formation of Schiff bases … intermediates formed
from weakly basic amines is aided by acid and base … strongly basic amines may also occur …

Equilibrium in formation and conformational isomerization of imines derived from isobutyraldehyde and saturated aliphatic primary amines

J Hine, CY Yeh - Journal of the American Chemical Society, 1967 - ACS Publications
… of the equilibrium constant for imine formation from a saturated aliphatic aldehyde and an
aliphatic amine. … Our results may be summarized by stating that the equilibrium constant

Extraction of monocarboxylic acids with trioctylamine: equilibria and correlation of apparent reactive equilibrium constant

W Qin, Z Li, Y Dai - Industrial & engineering chemistry research, 2003 - ACS Publications
… Long-chain aliphatic amines are effective extractants for the separation of carboxylic acids
… interactions between the amines and the acid molecules to form acidamine complexes in …

Acid-base reactions in concentrated aqueous quaternary ammonium salt solutions. I. Strong acids and bases, carboxylic acids, amines, and phenol

J Steigman, D Sussman - Journal of the American Chemical …, 1967 - ACS Publications
… The aliphatic tertiary amines, which are least capable of hydrogen bonding to water, show
a … The alkanolamines, which are weaker bases in water than their simple aliphatic amine