Kinetics of docking in postnucleation stages of self-assembly

RA Garza-López, P Bouchard, G Nicolis… - The Journal of …, 2008 - pubs.aip.org
In a previous study, the early stages of self-assembly in nanophase materials were explored
by coupling a kinetic mean-field analysis with a lattice-based stochastic theory [JJ Kozak et …

Modeling the early stages of self-assembly in nanophase materials. II. Role of symmetry and dimensionality

JJ Kozak, G Nicolis - The Journal of chemical physics, 2011 - pubs.aip.org
We study the early stages of self-assembly of elementary building blocks of nanophase
materials, considering explicitly their structure and the symmetry and the dimensionality of …

Modeling the early stages of self-assembly in nanophase materials

JJ Kozak, C Nicolis, G Nicolis - The Journal of chemical physics, 2007 - pubs.aip.org
The early stages of self-assembly of the elementary building blocks of nanophase materials
are studied. The relative roles of entropic and energetic factors in determining the relative …

Limit of validity of Ostwald's rule of stages in a statistical mechanical model of crystallization

LO Hedges, S Whitelam - The Journal of chemical physics, 2011 - pubs.aip.org
We have only rules of thumb with which to predict how a material will crystallize, chief
among which is Ostwald's rule of stages. It states that the first phase to appear upon …

Mesoscopic impurities expose a nucleation-limited regime of crystal growth

M Sleutel, JF Lutsko, D Maes, AES Van Driessche - Physical review letters, 2015 - APS
Nanoscale self-assembly is naturally subject to impediments at the nanoscale. The recently
developed ability to follow processes at the molecular level forces us to resolve older …

The statistical mechanics of dynamic pathways to self-assembly

S Whitelam, RL Jack - Annual review of physical chemistry, 2015 - annualreviews.org
This review describes some important physical characteristics of the pathways (ie,
dynamical processes) by which molecular, nanoscale, and micrometer-scale self-assembly …

Stochastic lag time in nucleated linear self-assembly

NS Tiwari, P van der Schoot - The Journal of Chemical Physics, 2016 - pubs.aip.org
Protein aggregation is of great importance in biology, eg, in amyloid fibrillation. The
aggregation processes that occur at the cellular scale must be highly stochastic in nature …

A molecular conformational change induced self-assembly: from randomness to order

W Xu, C Zhang, H Gersen, Q Sun, H Kong… - Chemical …, 2013 - pubs.rsc.org
From an interplay of high-resolution scanning tunneling microscopy (STM) imaging and
density functional theory (DFT) calculations we reveal how a molecular conformational …

Host–guest chemistry under confinement: peeking at early self-assembly events

R Steeno, A Minoia, R Lazzaroni, KS Mali… - Chemical …, 2022 - pubs.rsc.org
Host–guest chemistry under confinement: peeking at early self-assembly events - Chemical
Communications (RSC Publishing) DOI:10.1039/D1CC07206D Royal Society of Chemistry View …

Explaining the transition from diffusion limited to reaction limited surface assembly of molecular species through spatial variations

KM Carroll, AW Knoll, H Wolf, U Duerig - Langmuir, 2018 - ACS Publications
Surface assembly is often decomposed into two classes: diffusion and reaction limited
processes. The transition between the two cases is complex because the dynamics are so …