Solvation-driven electrochemical actuation
We demonstrate a novel principle of contactless actuation for ionic membranes in salt
solution based on solvation. Actuation is driven by differential swelling of the sides of the …
solution based on solvation. Actuation is driven by differential swelling of the sides of the …
Experimental evidence of the electrostatic contribution to the bending rigidity of charged membranes
We address the issue of the origin of the bending rigidity of a charged membrane formed
from amphiphilic molecules. Electrostatic effects are investigated by direct measurement of …
from amphiphilic molecules. Electrostatic effects are investigated by direct measurement of …
Solvation‐Driven Actuation of Anion‐Exchange Membranes
Ion‐exchange membranes, conventionally utilized in separation processes of electrolyte
solutions, are electroactive polymers that display a unique coupling between …
solutions, are electroactive polymers that display a unique coupling between …
A non-ideal solution theory for the mechanics and electrochemistry of charged membranes
Understanding how ions and solvent molecules migrate within charged membranes is
fundamental for advancing the analysis of biological membranes and the design of energy …
fundamental for advancing the analysis of biological membranes and the design of energy …
Inversion of solvent migration in charged membranes
We theoretically demonstrate the possibility of inversion of solvent migration in charged
membranes, opposing osmosis. Inversion of solvent migration is ascribed to the finite …
membranes, opposing osmosis. Inversion of solvent migration is ascribed to the finite …
Contactless actuation of perfluorinated ionomer membranes in salt solution: an experimental investigation
A variety of modeling frameworks have been proposed for ionic polymer metal composites
(IPMCs), but the physical underpinnings of their actuation remain elusive. A critical step …
(IPMCs), but the physical underpinnings of their actuation remain elusive. A critical step …
Charge dynamics and bending actuation in Aquivion membrane swelled with ionic liquids
The actuation strain and speed of ionic electroactive polymer (EAP) actuators are mainly
determined by the charge transport through the actuators and excess ion storage near the …
determined by the charge transport through the actuators and excess ion storage near the …
Complex fluids with mobile charge-regulating macro-ions
T Markovich, D Andelman, R Podgornik - Europhysics Letters, 2018 - iopscience.iop.org
We generalize the concept of charge regulation of ionic solutions, and apply it to complex
fluids with mobile macro-ions having internal non-electrostatic degrees of freedom. The …
fluids with mobile macro-ions having internal non-electrostatic degrees of freedom. The …
Evidence of counterion migration in ionic polymer actuators via investigation of electromechanical performance
Functional ionomeric polymer membranes are the backbone of a wide range of ionic
devices; the mobility of ions through the ionomeric membrane is the principle of operation of …
devices; the mobility of ions through the ionomeric membrane is the principle of operation of …
Electroelastic coupling between membrane surface fluctuations and membrane-embedded charges: Continuum multidielectric treatment
The coupling of electric fields and charges with membrane-water interfacial fluctuations
affects membrane electroporation, ionic conductance, and voltage gating. A modified …
affects membrane electroporation, ionic conductance, and voltage gating. A modified …