Solvation-driven electrochemical actuation

A Boldini, Y Cha, M Porfiri - Physical review letters, 2021 - APS
We demonstrate a novel principle of contactless actuation for ionic membranes in salt
solution based on solvation. Actuation is driven by differential swelling of the sides of the …

Experimental evidence of the electrostatic contribution to the bending rigidity of charged membranes

N Delorme, JF Bardeau, D Carrière… - The Journal of …, 2007 - ACS Publications
We address the issue of the origin of the bending rigidity of a charged membrane formed
from amphiphilic molecules. Electrostatic effects are investigated by direct measurement of …

Solvation‐Driven Actuation of Anion‐Exchange Membranes

N Ulbricht, A Boldini, C Bae… - Advanced Materials …, 2022 - Wiley Online Library
Ion‐exchange membranes, conventionally utilized in separation processes of electrolyte
solutions, are electroactive polymers that display a unique coupling between …

A non-ideal solution theory for the mechanics and electrochemistry of charged membranes

A Boldini, M Porfiri - npj Computational Materials, 2022 - nature.com
Understanding how ions and solvent molecules migrate within charged membranes is
fundamental for advancing the analysis of biological membranes and the design of energy …

Inversion of solvent migration in charged membranes

A Boldini, M Porfiri - Physical Review Letters, 2021 - APS
We theoretically demonstrate the possibility of inversion of solvent migration in charged
membranes, opposing osmosis. Inversion of solvent migration is ascribed to the finite …

Contactless actuation of perfluorinated ionomer membranes in salt solution: an experimental investigation

A Boldini, M Rosen, Y Cha, M Porfiri - Scientific reports, 2019 - nature.com
A variety of modeling frameworks have been proposed for ionic polymer metal composites
(IPMCs), but the physical underpinnings of their actuation remain elusive. A critical step …

Charge dynamics and bending actuation in Aquivion membrane swelled with ionic liquids

J Lin, Y Liu, QM Zhang - Polymer, 2011 - Elsevier
The actuation strain and speed of ionic electroactive polymer (EAP) actuators are mainly
determined by the charge transport through the actuators and excess ion storage near the …

Complex fluids with mobile charge-regulating macro-ions

T Markovich, D Andelman, R Podgornik - Europhysics Letters, 2018 - iopscience.iop.org
We generalize the concept of charge regulation of ionic solutions, and apply it to complex
fluids with mobile macro-ions having internal non-electrostatic degrees of freedom. The …

Evidence of counterion migration in ionic polymer actuators via investigation of electromechanical performance

W Hong, C Meis, JR Heflin, R Montazami - Sensors and Actuators B …, 2014 - Elsevier
Functional ionomeric polymer membranes are the backbone of a wide range of ionic
devices; the mobility of ions through the ionomeric membrane is the principle of operation of …

Electroelastic coupling between membrane surface fluctuations and membrane-embedded charges: Continuum multidielectric treatment

GV Miloshevsky, A Hassanein, MB Partenskii… - The Journal of …, 2010 - pubs.aip.org
The coupling of electric fields and charges with membrane-water interfacial fluctuations
affects membrane electroporation, ionic conductance, and voltage gating. A modified …