X), where X is the fraction neutral-ized, against the observed millivoltage value. The plots of
all solvents except ethylene dichloride are linear. The simple interpretation of E\/t as a …

Free energies, enthalpies, and entropies of ionization for a series of «-substituted 4-
picolinium ions in anhydrous dimethylformamide solution havebeen determined by the …

Introduction It is well known that acetonitrile is an excellent differentiating solvent for acid-
base titrations. The main cause of the stronglydifferentiating nature of acetonitrile is the …

The potentiometric method, employing the glass electrode, has been applied to the
determination of the acidities of a series of benzoic acids, several hydrocarbon acids, and …

In recent years, acid dissociation constants have become increasingly important as tools in
determining molecular structure and in solving questions of organic theory (1, 2). Many …

Acetonitrile is much more suitable for determination of the protonation constant K¡ BH+ of
very weak bases than is water (sulfolane, which is a considerably weaker base than AN, is …

V/„/n in which a denotes the activity of the component, c the concentration, Ib the basic form
and Ia the acid form of the indicator, A and B the acid and basic forms of the buffer, K'the …

In a previous paper relative acid strengths in n-butyl alcohol (13), determined by the
colorimetric method, were reported at low ion concentrations. These results were used …

Measurements of base strength are reported for p-toluidine, aniline, p-chloroaniline and m-
nitroaniline in dioxan-water mixtures at 25'C. The effect of a substituent on the variation in …

In acetonitrile as solvent, the stronger nitrogen bases, B, form 1: 1 and also higher hydrogen-
bonded complexes with their conjugate acids, BH+. Formation constants for these …