Enzymic transfer of 6-modified d-galactosyl residues: synthesis of biantennary penta-and hepta-saccharides having two 6-deoxy-d-galactose residues at the …

Y Kajihara, T Endo, H Ogasawara, H Kodama… - Carbohydrate …, 1995 - Elsevier
UDP-6-Deoxy-d-galactose and UDP-6-deoxy-6-fluoro-d-galactose were synthesized and
their transfer to 2-acetamido-2-deoxy-d-glucose (N-acetyl-d-glucosamine) by β-(1→ 4) …

Synthesis of UDP-6-deoxy-and-6-fluoro-D-galactoses and their enzymatic glycosyl transfer to mono-and biantennary carbohydrate chains

H Kodama, Y Kajihara, T Endo, H Hashimoto - Tetrahedron letters, 1993 - Elsevier
Glycosylation with chemically prepared UDP-6-deoxy-D-galactose and its 6-fluoro analog
using bovine (1–4)-β-D-galactosyltransferase was demonstrated to be effective enough for …

Transfer of D-galactosyl groups to 6-O-substituted 2-acetamido-2-deoxy-D-glucose residues by use of bovine D-galactosyltransferase

MM Palcic, OP Srivastava, O Hindsgaul - Carbohydrate research, 1987 - Elsevier
Bovine d-galactosyltransferase was found to transfer d-galactose from UDP-galactose to 6-O-
substituted 2-acetamido-2-deoxy-β-d-glucopyranosides. The resulting 6-O-substituted N …

Chemical synthesis and kinetic characterization of UDP-2-deoxy-d-lyxo-hexose (“UDP-2-deoxy-d-galactose”), a donor-substrate for β-(1→ 4)-d-galactosyltransferase

G Srivastava, O Hindsgaul, MM Palcic - Carbohydrate research, 1993 - Elsevier
Abstract Bovine β-(1→ 4)-galactosyltransferase (GalT) transfers galactose from UDP-
galactose to β-d-GlcpNAc-terminating oligosaccharides to produce N-acetyllactosamine …

Convenient Synthesis of β-(1→ 3)-Galactosyl Disaccharide α-Glycoside and Its Analogs as Mimic Units of Mucin-Type Carbohydrate

T Murata, T Itoh, Y Hayakawa, T Usui - The journal of biochemistry, 1996 - jstage.jst.go.jp
Received for publication, June 20, 1996 ƒÀ-Galactosidase from porcine testes induced
regioselective transglycosylation from lactose to the 3-position of 2-acetamido glycosides …

Synthesis of benzyl O-(2-O-methyl-β-d-galactopyranosyl)-(1→ 3)-2-acetamido-2-deoxy-β-d-glucopyranoside [benzyl 2′-O-methyllacto-N-bioside I], and its higher …

AK Sarkar, RK Jain, KL Matta - Carbohydrate research, 1990 - Elsevier
Abstract Treatment of benzyl O-β-d-galactopyranosyl-(1→ 3)-2-acetamido-2-deoxy-4, 6-O-
isopropylidene-β-d-glucopyranoside with tert-butychlorodiphenylsilane afforded the 6′-O …

Synthesis of a cyanoethylidene derivative of 3, 6-anhydro-d-galactose and its application as glycosyl donor

C Vogel, GM Torres, H Reinke, D Michalik, A Voss - Carbohydrate research, 2007 - Elsevier
Starting from 1, 2, 4-tri-O-acetyl-3, 6-anhydro-α-d-galactopyranose, 4-O-acetyl-3, 6-anhydro-
1, 2-O-(1-cyanoethylidene)-α-d-galactopyranose (7) was synthesized by treatment with …

Synthesis of the disaccharide 6-O-β-D-galactopyranosyl-2-acetamido-2-deoxy-D-galactose using immobilized β-galactosidase

L Hedbys, PO Larsson, K Mosbach… - … and biophysical research …, 1984 - Elsevier
Abstract The disaccharide 6-O-β-d-galactopyranosyl-2-acetamido-2-deoxy-d-galactose has
been synthesized by transfer of the β-d-galactopyranosyl residue from lactose to 2 …

The synthesis of 6-O-(2-acetamido-2-deoxy-β-D-galactopyranosyl)-D-galactose by inversion of configuration

K Miyai, RW Jeanloz - Carbohydrate Research, 1972 - Elsevier
As a model synthesis for the preparation of oligosaccharides containing the 2-acetamido-2-
deoxy-D-galactopyranosyl group, 6-O-(2-acetamido-2-deoxy-β-D-galactopyranosyl)-D …

UDP-6-deoxy-6-fluoro-α-d-galactose binds to two different galactosyltransferases, but neither can effectively catalyze transfer of the modified galactose to the …

CL Schengrund, P Kováč - Carbohydrate research, 1999 - Elsevier
The effect of substitution of the HO-6 of d-galactose with fluorine on the ability of α-(1→ 3)-
galactosyltransferase (EC 2.4. 1.151) and β-(1→ 4)-galactosyltransferase (EC 2.4. 1.22) to …