Practical dihydroxylation and C–C cleavage of unsaturated fatty acids

MA Oakley, S Woodward, K Coupland, D Parker… - Journal of Molecular …, 1999 - Elsevier
MA Oakley, S Woodward, K Coupland, D Parker, C Temple-Heald
Journal of Molecular Catalysis A: Chemical, 1999Elsevier
Unsaturated fatty acids [C8H17CH= CH (CH2) nCO2H](n= 7, 11) acids are cleanly
dihydroxylated by hydrogen peroxide in the presence of catalytic amounts of H2WO4. Under
molecular oxygen, in the presence of catalytic amounts of N-hydroxyphthalimide and Co
(acac) 3, the diols resulting from erucic (n= 11) and oleic (n= 7) acid undergo C–C cleavage.
Unsaturated fatty acids [C8H17CH=CH(CH2)nCO2H] (n=7, 11) acids are cleanly dihydroxylated by hydrogen peroxide in the presence of catalytic amounts of H2WO4. Under molecular oxygen, in the presence of catalytic amounts of N-hydroxyphthalimide and Co(acac)3, the diols resulting from erucic (n=11) and oleic (n=7) acid undergo C–C cleavage.
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